I just tried playing Syberia 1 & 2 on my windows 10. They installed but they won't play.
If you're using disc versions, they won't play on Windows 10 because the discs are crippled with SafeDisc DRM. Look for NoCD's (Google the name of the game and NoCD) or buy DRM-free versions. GOG claims their versions of Syberia 1 and 2 work on Windows 10. DotEMU and Steam only list up to Windows 7, but that may be because Windows 10 is changing all the time and they don't want to guarantee the game on a moving target. NoCD's are free but you have to get the right version for your particular version of the game.